Possible Clues:

• A sailor, I? O, I can climb from from the word go!
• From the beginning in Latin
• Latin phrase for 'from the beginning'
• A book in Italian I love from the outset
• Undercoat for metal/wood
• Sailor is in it with Lionheart from the beginning in Rome
• From Roman beginnings, first characters get in close to it at Number 10
• Afresh, in Latin
• Throw it away into main road! That adds nothing from the start
• Academy can get editions from the centre in Rome from the beginning