Possible Clues:

• Player across the diamond from I Don't Know
• Branch of the U.N. in 2020 news
• '___ goes there?'
• It becomes another question when its first letter is moved to the end
• First word of many questions
• With 52-Across, common end for a riddle
• Start of many a 'Jeopardy!' answer
• Start of many a "Jeopardy!" answer
• Starting word of many sentences
• A question of identification